There is a small difference. The twin wall polly traps heated air between the layers and helps warm a greenhouse but without a heat source at night the heat will be released just as fast as flat panel. The doubled wall will help colder zones heat the greenhouse faster in spring and fall during the day. Hope this helps. Happy New Year.
I just did a search "plexiglass for greenhouse". Tells what kind recommended, thickness, etc. It has a lot going for it. Google it. Can also do a comparison to polycarbonate with google.